Synthetic Polymer MALDI Recipes Results

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Record 1 of 2

Record #:465
Class ID:2.4
Class Name:epoxy polymer
Polymer:epoxy resins
Matrix:dihydroxybenzoic acid (DHB) (27138-57-4)
Salt:sodium iodide (NaI)
Solvent:N/A
RecipeN/A

Penczek, S.; Kaluzynski, K.; Pretula, J., Addition of H3Po4 to Diglycidyl Ethers of Bisphenol A: Kinetics and Product Structure, Journal of Applied Polymer Science, 105, 1, 2007, 246-254.

doi:10.1002/app.26087

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Record 2 of 2

Record #:1140
Class ID:2.4
Class Name:epoxy polymer
Polymer:epoxy resins
Matrices:dithranol (1143-38-0)
trans-2-[3-(4-tert-butylphenyl)-2-methyl-2-propenylidene]malononitrile (300364-84-5)
dihydroxybenzoic acid (27138-57-4)
indoleacrylic acid (IAA) (29953-71-7)
2-(4'-hydroxybenzeneazo)benzoic acid (HABA) (1634-82-8)
Salt:NaI, KCl, LiTFA
Solvent:tetrahydrofuran, acetone
Recipe[Analyte] solution (10 mg/mL in THF) was mixed with various matrixes (dithranol, DCTB, DHB, IAA, HABA; 20 up to 40 mg/mL in THF) and salt additives (NaI, KCl, LiTFA; 100 mg/mL in acetone or THF) in the volume ratios 1:3:1 (v/v/v) and spotted onto a MALDI target (dried-droplet method).(26) The best spectra (good signal-to-noise levels, 25, and adequate resolution, 23 654) were obtained by using the matrix dithranol and the salt additives NaI or LiTFA,

Crecelius, A.C.; Steinacker, R.; Meier, A.; Alexandrov, T.; Vitz, J.; Schubert, U.S., Application of Matrix-Assisted Laser Desorption/Lonization Mass Spectrometric Imaging for Photolithographic Structuring, Analytical Chemistry, 84, 16, 2012, 6921-6925.

doi:10.1021/ac301616v

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